Product ID:OFF WINDSHIELD DE-ICER SPRAY
MSDS Date:01/01/1987
FSC:6850
NIIN:00N010567
MSDS Number: BHNVJ

STATE CHEMICAL MANUFACTURING CO

3100 HAMILTON AVENUE
CLEVELAND, OH 44114

Emergency Phone: 216-861-7114

Info Phone: 216-861-7114

Cage: 53798

STATE CHEMICAL MANUFACTURING CO.

CLEVELAND, OH 44114-3701 US

Telephone: 216-861-7114

Cage: 53798

ETHYLENE GLYCOL (SARA III)

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: <10%

OSHA PEL C 50 PPM

ACGIH TLV: C 50 PPM,VAPOR; 9192

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: >70%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

Fraction By Weight: <20%

OSHA PEL 5000 PPM

ACGIH TLV: 5000PPM/30000STEL;93

LD50 LC50 Mixture:N/K
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:DANGER:POISON.MAY BE FATAL OR CAUSE
BLINDNESS IF SWALLOWED.CHRONIC:METHANOL POISONING.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:MAY CAUSE IRRITATION.SKIN:POSSIBLE
IRRITATION OR DRYING AND CRACKING.INGESTION:POISON.MAY BE FATAL OR
CAUSE BLINDNESS IF SWALLOWED.INHALATION:VAPOR HARMFUL.MAY CAUSE
HEADACHE,NAUSEA,VOMITING.CHRO NIC HEALTH EFFECTS:METHANOL
POISONING.
Medical Cond Aggravated by Exposure:N/K

First Aid:EYES:FLUSH IMMED W/ PLENTY OF COOL WATER FOR AT LEAST 15
MIN.SEEK MED ATTN.SKIN:WASH W/ SOAP & WATER THOROUGHLY & SEEK MED
ATTN.INGEST:INDUCE VOMIT.GIVE 1 TABLESPOON SYRUP OF IPECAC PLUS AT
LEAST 1 CU P OF WATER.REPEAT ONCE ONLY IF NO VOMITING OCCURS WITHIN
20 MIN.CALL MD IMEDIATELY.THIS IS ESSENTIAL.INHALATION:REMOVE
PERSON TO FRESH AIR.SEEK MEDICAL ATTENTION.

Flash Point:NO FLASHBACK
Lower Limits:N/K
Upper Limits:N/K
Extinguishing Media:HIGH EXPANSION FOAM,DRY CHEMICAL OR CARBON DIOXIDE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .KEEP CANS COOL.USE SHIELDING TO PROTECT
PERSONNEL FROM VENTING,RUPTURING OR BURSTING CONTRS.
Unusual Fire/Explosion Hazard:AT TEMP >120F CONTRS MAY VENT,RUPTURE OR
BURST.FLAMM.POSITIVE FLAME EXTENSION.NO FLASHBACK.BURNING MAY CAUSE
FORMATION OF CARBON DIOXIDE &/OR CARBON MONOXIDE.

Spill Release Procedures:REMOVE SOURCE OF HEAT,SPARKS OR
FLAME.VENTILATE AREA.WIPE UP EXCESS OR FLUSH THOROUGHLY WITH
WATER.USE OUTDOORS.
Neutralizing Agent:N/K

Handling and Storage Precautions:DANGER-POISON:POSS DEATH/BLINDNESS.VAP
HARMFUL.FLAMM.DO NOT STORE NEAR HEAT,SPARKS,OPEN FLAME.DO NOT STORE
>120F,49C,SUCH AS IN SUNLIGHT.(SEE SUPP DA)
Other Precautions:READ & FOLLOW ALL LABEL DIRECTIONS & PRECAUTIONS
BEFORE USING THE PRODUCT.THESE PRODUCTS ARE INTENDED FOR INDUSTRIAL
& INSTITUTIONAL USE ONLY.NOT INTENDED FOR HOUSEHOLD USE OR
RESALE.KEEP OUT OF REACH OF CHILDREN.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .NONE REQUIRED.USE OUTDOORS ONLY.
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:OPTIONAL
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE
Work Hygienic Practices:WASH AFTER HANDLING & BEFORE EATING,DRINKING OR
SMOKING.
Supplemental Safety and Health
% VOLATILE BY WEIGHT:100.HNDLG/STOR PREC:AVOID CONTACT W/
SKIN,EYES,CLTHG.CANNOT BE MADE NONPOISONOUS.DO NOT OVER APPLY.DO
NOT START WIPER BLADES UNTIL ICE HAS BEEN THOROUGHLY MELTED.WASH
AFTER HANDLI NG AND BEFORE EATING,DRINKING OR SMOKING.USE OUTDOORS
ONLY.

Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:N/K
Vapor Density:N/K
Spec Gravity:0.86 (WATER=1)
Evaporation Rate & Reference:N/K
Solubility in Water:COMPLETE
Appearance and Odor:WATER-WHITE AEROSOL SPRAY WITH A MILD ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:HEAT,SPARKS OR OPEN FLAME.
Hazardous Decomposition Products:BURNING MAY RESULT IN FORMATION OF
CARBON DIOXIDE AND/OR CARBON MONOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .DO NOT PUNCTURE OR INCINERATE
CANS.GIVE CANS TO A DISPOSAL AGENCY EQUIPPED TO SAFELY HANDLE AND
DISPOSE OF PRESSURIZED CO NTAINERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.